Recently I was ask about the suggestion of a good SharePoint 2010 end user training materials. I searched the net and I firsts stopped on a Microsoft SharePoint official site on their SharePoint 2010 Resources for End Users.
Browsing trough content I found great videos about SharePoint features and different ways of usage. Also there are complete SharePoint End User Training Courses covering different Topics for SharePoint features. Lastly I found downloadable PowerPoint presentations with videos in them. Presentations are great and can be stored on the company local SharePoint site from where users can open them and learn how can they improve their day to day work performance with SharePoint 2010.
Here are some of the links to the PowerPoint presentation I suggest for the start:
http://0.mk/sp2010_t1 - SharePoint pages I: An introduction http://0.mk/sp2010_t2 - SharePoint lists I: An introduction http://0.mk/sp2010_t3 - SharePoint document libraries I - An introduction http://0.mk/sp2010_t4 - Share information in a central place
When organizing end user training for the employees in you company, there is always a good practice to create a site where all users will have Contribute permissions. There they can try what they saw and learned from the trainings.